Skip to main content

Introduction to Chemistry: 7.0 Introduction

Introduction to Chemistry
7.0 Introduction
    • Notifications
    • Privacy
  • Project HomeNatural Sciences Collection: Anatomy, Biology, and Chemistry
  • Projects
  • Learn more about Manifold

Notes

Show the following:

  • Annotations
  • Resources
Search within:

Adjust appearance:

  • font
    Font style
  • color scheme
  • Margins
table of contents
  1. Cover
  2. Title Page
  3. Copyright
  4. Table Of Contents
  5. Introduction
  6. Preface
  7. Acknowledgements
  8. About the Authors
  9. Chapter 1. Chemistry: An Experimental Science
    1. 1.0 Introduction
    2. 1.1 Chemistry in Context
    3. 1.2 Phases and Classification of Matter
    4. 1.3 Physical and Chemical Properties
  10. Chapter 2. Atoms, Molecules, and Ions
    1. 2.0 Introduction
    2. 2.1 Atomic Theory
    3. 2.2 Beyond Dalton’s Atomic Theory
    4. 2.3 Atomic Structure and Symbols
    5. 2.4 Chemical Formulas
    6. 2.5 The Periodic Table
  11. Chapter 3. Ions, Bonding and Compound Formation
    1. 3.0 Introduction
    2. 3.1 Ionic and Molecular Compounds
    3. 3.2 Nomenclature of Simple Ionic and Molecular Compounds
  12. Chapter 4. Chemical Reactions and Equations
    1. 4.0 Introduction
    2. 4.1 Writing and Balancing Chemical Equations
    3. 4.2 Precipitation Reactions
    4. 4.3 Acid-Base Reactions
    5. 4.4 Oxidation-Reduction Reactions
  13. Chapter 5. Bridging the Macroscopic and Microscopic Realms
    1. 5.0 Introduction
    2. 5.1 Formula Mass
    3. 5.2 The Mole
    4. 5.3 Reaction Stoichiometry
    5. 5.4 Limiting Reactant and Reaction Yields
  14. Chapter 6. Solutions
    1. 6.0 Introduction
    2. 6.1 Solution Concentration and Molarity
    3. 6.2 Other Concentration Units
  15. Chapter 7. Chemical Bonding and Lewis Structures
    1. 7.0 Introduction
    2. 7.1 Covalent Bonding
    3. 7.2 Lewis Dot Structures
    4. 7.3 Lewis Structures and Covalent Compounds
  16. Additional Reading: Electronic Structure of Atoms
    1. 8.0 Introduction
    2. 8.1 Electromagnetic Energy
    3. 8.2 Quantization of the Energy of Electrons
    4. 8.3 Development of Quantum Theory
    5. 8.4 Electronic Structure of Atoms
    6. 8.5 Periodic Trends
  17. Chapter LAB1. Making Measurements
    1. Introduction
    2. LAB1.1 Expressing Numbers
    3. LAB1.2 Measurements and Units
    4. LAB1.3 Measurement Uncertainty, Accuracy, and Precision
    5. LAB1.4 Mathematical Treatment of Measurement Results – Unit Conversions
    6. LAB1.5 Density – A Derived Unit and Conversion Factor
  18. Appendix
  19. Appendix A: The Periodic Table
  20. Appendix B: Essential Mathematics
  21. Appendix C: Units and Conversion Factors
  22. Appendix D: Fundamental Physical Constants

27

7.0 Introduction

It has long been known that pure carbon occurs in different forms (allotropes) including graphite and diamonds.

Graphite is brittle, whereas diamond is the hardest natural material known on Earth. Yet both are just pure carbon. What is special about this element that makes these two forms of carbon so different?

Bonds. Chemical bonds!

In graphite, each carbon is bonded to three other carbons to form a flat sheets of carbon lattices which are form layers.  These layers, called graphene, are attracted to each other through Van der Waals forces, a type of intermolecular force.  Graphite is brittle because these intermolecular forces are relatively weak.

In a perfect diamond crystal, each C atom makes four connections—bonds—to four other C atoms in a three-dimensional matrix. Four is the greatest number of bonds that is commonly made by atoms, so C atoms maximize their interactions with other atoms. This three-dimensional array of connections extends throughout the diamond crystal, making it essentially one large molecule. Breaking a diamond means breaking every bond at once.

Figure 1. Diamond and graphite samples with their respective structures. The bottom right formation of carbon is what is known as “graphene,” characterized by infinite, single atom sheets of carbon. By User:Itub (Self-made derivative work (see below)) [GFDL (http://www.gnu.org/copyleft/fdl.html) or CC-BY-SA-3.0 (http://creativecommons.org/licenses/by-sa/3.0/)], via Wikimedia Commons

It was not until 1985 that a new form of carbon was recognized: buckminsterfullerene, commonly known as a “buckyball.” This molecule was named after the architect and inventor R. Buckminster Fuller (1895–1983), whose signature architectural design was the geodesic dome, characterized by a lattice shell structure supporting a spherical surface. Experimental evidence revealed the formula, C60, and then scientists determined how 60 carbon atoms could form one symmetric, stable molecule. They were guided by bonding theory—the topic of this chapter—which explains how individual atoms connect to form more complex structures.

Figure 2. Eight allotropes of carbon: a) diamond, b) graphite, c) Ionsdaleite, d) C60 buckminsterfullerene, e) C540, Fullerite, f) C70, g) amorphous carbon, and h) single-walled carbon nanotube.By Created by Michael Ströck (mstroeck) (Created by Michael Ströck (mstroeck)) [GFDL (http://www.gnu.org/copyleft/fdl.html), CC-BY-SA-3.0 (http://creativecommons.org/licenses/by-sa/3.0/) or CC BY-SA 2.5 (https://creativecommons.org/licenses/by-sa/2.5)], via Wikimedia Commons

Annotate

Next Chapter
7.1 Covalent Bonding
PreviousNext
Chemistry
Copyright © 2020 by Carol Higginbotham. Introduction to Chemistry by Carol Higginbotham is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License, except where otherwise noted.
Powered by Manifold Scholarship. Learn more at
Opens in new tab or windowmanifoldapp.org