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Introduction to Chemistry: Appendix B: Essential Mathematics

Introduction to Chemistry
Appendix B: Essential Mathematics
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table of contents
  1. Cover
  2. Title Page
  3. Copyright
  4. Table Of Contents
  5. Introduction
  6. Preface
  7. Acknowledgements
  8. About the Authors
  9. Chapter 1. Chemistry: An Experimental Science
    1. 1.0 Introduction
    2. 1.1 Chemistry in Context
    3. 1.2 Phases and Classification of Matter
    4. 1.3 Physical and Chemical Properties
  10. Chapter 2. Atoms, Molecules, and Ions
    1. 2.0 Introduction
    2. 2.1 Atomic Theory
    3. 2.2 Beyond Dalton’s Atomic Theory
    4. 2.3 Atomic Structure and Symbols
    5. 2.4 Chemical Formulas
    6. 2.5 The Periodic Table
  11. Chapter 3. Ions, Bonding and Compound Formation
    1. 3.0 Introduction
    2. 3.1 Ionic and Molecular Compounds
    3. 3.2 Nomenclature of Simple Ionic and Molecular Compounds
  12. Chapter 4. Chemical Reactions and Equations
    1. 4.0 Introduction
    2. 4.1 Writing and Balancing Chemical Equations
    3. 4.2 Precipitation Reactions
    4. 4.3 Acid-Base Reactions
    5. 4.4 Oxidation-Reduction Reactions
  13. Chapter 5. Bridging the Macroscopic and Microscopic Realms
    1. 5.0 Introduction
    2. 5.1 Formula Mass
    3. 5.2 The Mole
    4. 5.3 Reaction Stoichiometry
    5. 5.4 Limiting Reactant and Reaction Yields
  14. Chapter 6. Solutions
    1. 6.0 Introduction
    2. 6.1 Solution Concentration and Molarity
    3. 6.2 Other Concentration Units
  15. Chapter 7. Chemical Bonding and Lewis Structures
    1. 7.0 Introduction
    2. 7.1 Covalent Bonding
    3. 7.2 Lewis Dot Structures
    4. 7.3 Lewis Structures and Covalent Compounds
  16. Additional Reading: Electronic Structure of Atoms
    1. 8.0 Introduction
    2. 8.1 Electromagnetic Energy
    3. 8.2 Quantization of the Energy of Electrons
    4. 8.3 Development of Quantum Theory
    5. 8.4 Electronic Structure of Atoms
    6. 8.5 Periodic Trends
  17. Chapter LAB1. Making Measurements
    1. Introduction
    2. LAB1.1 Expressing Numbers
    3. LAB1.2 Measurements and Units
    4. LAB1.3 Measurement Uncertainty, Accuracy, and Precision
    5. LAB1.4 Mathematical Treatment of Measurement Results – Unit Conversions
    6. LAB1.5 Density – A Derived Unit and Conversion Factor
  18. Appendix
  19. Appendix A: The Periodic Table
  20. Appendix B: Essential Mathematics
  21. Appendix C: Units and Conversion Factors
  22. Appendix D: Fundamental Physical Constants

3

Appendix B: Essential Mathematics

Appendix B: Essential Mathematics

Exponential Arithmetic

Exponential notation is used to express very large and very small numbers as a product of two numbers. The first number of the product, the digit term, is usually a number not less than 1 and not greater than 10. The second number of the product, the exponential term, is written as 10 with an exponent. Some examples of exponential notation are:

\begin{array}{r @{{}={}} l} 1000 & 1\;\times\;10^3 \\[0.75em] 100 & 1\;\times\;10^2 \\[0.75em] 10 & 1\;\times\;10^1 \\[0.75em] 1 & 1\;\times\;10^0 \\[0.75em] 0.1 & 1\;\times\;10^{-1} \\[0.75em] 0.001 & 1\;\times\;10^{-3} \\[0.75em] 2386 & 2.386\;\times\;1000 = 2.386\;\times\;10^3 \\[0.75em] 0.123 & 1.23\;\times\;0.1 = 1.23\;\times\;10^{-1} \end{array}

The power (exponent) of 10 is equal to the number of places the decimal is shifted to give the digit number. The exponential method is particularly useful notation for every large and very small numbers. For example, 1,230,000,000 = 1.23 × 109, and 0.00000000036 = 3.6 × 10−10.

Addition of Exponentials

Convert all numbers to the same power of 10, add the digit terms of the numbers, and if appropriate, convert the digit term back to a number between 1 and 10 by adjusting the exponential term.

Example 1

Adding Exponentials
Add 5.00 × 10−5 and 3.00 × 10−3.

Solution

3.00\;\times\;10^{-3} = 300\;\times\;10^{-5}
(5.00\;\times\;10^{-5})\;+\;(300\;\times\;10^{-5}) = 305\;\times\;10^{-5} = 3.05\;\times\;10^{-3}

Subtraction of Exponentials

Convert all numbers to the same power of 10, take the difference of the digit terms, and if appropriate, convert the digit term back to a number between 1 and 10 by adjusting the exponential term.

Example 2

Subtracting Exponentials
Subtract 4.0 × 10−7 from 5.0 × 10−6.

Solution

4.0\;\times\;10^{-7} = 0.40\;\times\;10^{-6}
(5.0\;\times\;10^{-6})\;-\;(0.40\;\times\;10^{-6}) = 4.6\;\times\;10^{-6}

Multiplication of Exponentials

Multiply the digit terms in the usual way and add the exponents of the exponential terms.

Example 3

Multiplying Exponentials
Multiply 4.2 × 10−8 by 2.0 × 103.

Solution

(4.2\;\times\;10^{-8})\;\times\;(2.0\;\times\;10^3) = (4.2\;\times\;2.0)\;\times\;10^{(-8)+(+3)} = 8.4\;\times\;10^{-5}

Division of Exponentials

Divide the digit term of the numerator by the digit term of the denominator and subtract the exponents of the exponential terms.

Example 4

Dividing Exponentials
Divide 3.6 × 105 by 6.0 × 10−4.

Solution

\frac{3.6\;\times\;10^{-5}}{6.0\;\times\;10^{-4}} = (\frac{3.6}{6.0})\;\times\;10^{(-5)-(-4)} = 0.60\;\times\;10^{-1} = 6.0\;\times\;10^{-2}

Squaring of Exponentials

Square the digit term in the usual way and multiply the exponent of the exponential term by 2.

Example 5

Squaring Exponentials
Square the number 4.0 × 10−6.

Solution

(4.0\;\times\;10^{-6})^2 = 4\;\times\;4\;\times\;10^{2\;\times\;(-6)} = 16\;\times\;10^{-12} = 1.6\;\times\;10^{-11}

Cubing of Exponentials

Cube the digit term in the usual way and multiply the exponent of the exponential term by 3.

Example 6

Cubing Exponentials
Cube the number 2 × 104.

Solution

(2\;\times\;10^4)^3 = 2\;\times\;2\;\times\;2\;\times\;10^{3\;\times\;4} = 8\;\times\; 10^{12}

Taking Square Roots of Exponentials

If necessary, decrease or increase the exponential term so that the power of 10 is evenly divisible by 2. Extract the square root of the digit term and divide the exponential term by 2.

Example 7

Finding the Square Root of Exponentials
Find the square root of 1.6 × 10−7.

Solution

1.6\;\times\;10^{-7} = 16\;\times\;10^{-8}
\sqrt{16\;\times\;10^{-8}} = \sqrt{16}\;\times\;\sqrt{10^{-8}} = \sqrt{16}\;\times\;\sqrt{10}^{-\frac{8}{2}} = 4.0\;\times\;10^{-4}

Significant Figures

A beekeeper reports that he has 525,341 bees. The last three figures of the number are obviously inaccurate, for during the time the keeper was counting the bees, some of them died and others hatched; this makes it quite difficult to determine the exact number of bees. It would have been more accurate if the beekeeper had reported the number 525,000. In other words, the last three figures are not significant, except to set the position of the decimal point. Their exact values have no meaning useful in this situation. In reporting any information as numbers, use only as many significant figures as the accuracy of the measurement warrants.

The importance of significant figures lies in their application to fundamental computation. In addition and subtraction, the sum or difference should contain as many digits to the right of the decimal as that in the least certain of the numbers used in the computation (indicated by underscoring in the following example).

Example 8

Addition and Subtraction with Significant Figures
Add 4.383 g and 0.0023 g.

Solution

\begin{array}{l} 4.38\underline{3}\;\text{g} \\ 0.002\underline{3}\;\text{g} \\ \hline 4.38\underline{5}\;\text{g} \end{array}

In multiplication and division, the product or quotient should contain no more digits than that in the factor containing the least number of significant figures.

Example 9

Multiplication and Division with Significant Figures
Multiply 0.6238 by 6.6.

Solution

0.623\underline{8}\;\times\;6.\underline{6} = 4.\underline{1}

When rounding numbers, increase the retained digit by 1 if it is followed by a number larger than 5 (“round up”). Do not change the retained digit if the digits that follow are less than 5 (“round down”). If the retained digit is followed by 5, round up if the retained digit is odd, or round down if it is even (after rounding, the retained digit will thus always be even).

Annotate

Next Chapter
Appendix C: Units and Conversion Factors
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Chemistry
Copyright © 2020 by Carol Higginbotham. Introduction to Chemistry by Carol Higginbotham is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License, except where otherwise noted.
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